Pore network characterization and fluid occurrence of shale reservoirs: State-of-the-art and future perspectives

Authors

  • Mengdi Sun* National Key Laboratory of Continental Shale Oil, Northeast Petroleum University, Daqing 163318, P. R. China(Email:sunmd@cug.edu.cn)
  • Jiajun Fu National Key Laboratory of Continental Shale Oil, Northeast Petroleum University, Daqing 163318, P. R. China
  • Qiming Wang National Key Laboratory of Deep Oil and Gas, China University Petroleum (East China), Qingdao 266580, P. R. China
  • Zhiye Gao* National Key Laboratory of Petroleum Resources and Engineering, China University of Petroleum, Beijing 102249, P. R. China(Email:gaozhiye@163.com)

Keywords:

Shale reservoir, pore characterization, fluid occurrence

Abstract

Due to the increasing energy consumption and the promoting of the carbon neutral target, the exploitation of shale oil and gas, as well as carbon dioxide sequestration and hydrogen storage using shale as caprock, has received enormous attention. As a foundation for these hotspots, the characterization of pore structure in shale reservoirs has been widely studied. In this paper, the application of fluid intrusion and radiation methods in the characterization of pore structure in shale reservoirs was systematically reviewed, and the merits and limitations of both methods were highlighted. Taking the Fengcheng shale as an example, a detailed investigation of the fluid occurrence state was conducted, indicating that the fluid occurrence state significantly impacts the exploitation of hydrocarbon from shale reservoirs. Furthermore, there needs to be a systematic of investigation of how the pore structure characteristics and inorganic components of shale reservoirs control the integrity and safety of CO2 and H2 storage. Moreover, confinement effect of nanopores in shale should be paid attention to in future research on carbon and hydrogen storage.

Document Type: Perspective

Cited as: Sun, M., Fu, J., Wang, Q., Gao, Z. Pore network characterization and fluid occurrence of shale reservoirs: State-of-the-art and future perspectives. Advances in Geo-Energy Research, 2024, 12(3): 161-167. https://doi.org/10.46690/ager.2024.06.01

References

Aghaei, H., Al-Yaseri, A., Toorajipour, A., et al. Host-rock and caprock wettability during hydrogen drainage: Im plications of hydrogen subsurface storage. Fuel, 2023, 351: 129048.

Al-Yaseri, A., Amao, A., Fatah, A. Experimental investigation of shale/hydrogen geochemical interactions. Fuel, 2023, 346: 128272.

Anovitz, L. M., Cole, D. R. Characterization and analysis of porosity and pore Structures. Reviews in Mineralogy and Geochemistry, 2015, 80(1): 61-164.

Curtis, M. E., Cardott, B. J., Sondergeld, C. H., et al. Development of organic porosity in the Woodford Shale with increasing thermal maturity. International Journal of Coal Geology, 2012, 103: 26-31.

Elsayed, M., Isah, A., Hiba, M., et al. A review on the applications of nuclear magnetic resonance (NMR) in the oil and gas industry: laboratory and field-scale measurements. Journal of Petroleum Exploration and Production Technology, 2022, 12(10): 2747-2784.

Froudakis, G. E. Hydrogen storage in nanotubes & nanostructures. Materials Today, 2011, 14(7-8): 324-328.

Gao, J., Li, X., Cheng, G., et al. Structural evolution and characterization of organic-rich shale from macroscopic to microscopic resolution: The significance of tectonic activity. Advances in Geo-Energy Research, 2023a, 10(2): 84-90.

Gao, Z., Duan, L., Jiang, Z., et al. Using laser scanning confocal microscopy combined with saturated oil experiment to investigate the pseudo in-situ occurrence mechanism of light and heavy components of shale oil in sub-micron scale. Journal of Petroleum Science and Engineering, 2023b, 220: 111234.

Gao, Z., Hu, Q. Estimating permeability using median porethroat radius obtained from mercury intrusion porosimetry. Journal of Geophysics and Engineering, 2013, 10(2): 025014.

Glorioso, J. C., Rattia, A. Unconventional reservoirs: Basic petrophysical concepts for shale gas. Paper SPE 153004 Present at the SPE/EAGE European Unconventional Resources Conference and Exhibition, Vienna, Austria, 20- 22 March, 2012.

Gong, D., Bai, L., Gao, Z., et al. Occurrence mechanisms of laminated-type and sandwich-type shale oil in the Fengcheng Formation of Mahu Sag, Junggar Basin. Energy & Fuels, 2023, 37(18): 13960-13975.

Hosseini, M., Arif, M., Keshavarz, A., et al. Neutron scattering: A subsurface application review. Earth-Science Reviews, 2021, 221: 103755.

Hu, Q., Wang, J. S. Y. Aqueous-phase diffusion in unsaturated geologic media: A review. Critical Reviews in Environmental Science and Technology, 2003, 33(3): 275-297.

Hu, Q., Wang, Q., Zhang, T., et al. Petrophysical properties of representative geological rocks encountered in carbon storage and utilization. Energy Reports, 2023, 9: 3661-3682.

Hu, T., Pang, X., Jiang, F., et al. Movable oil content evaluation of lacustrine organic-rich shales: Methods and a novel quantitative evaluation model. Earth-Science Reviews, 2021, 214: 103545.

Jiang, C., Wang, G., Song, L., et al. Identification of fluid types and their implications for petroleum exploration in the shale oil reservoir: A case study of the Fengcheng Formation in the Mahu Sag, Junggar Basin, Northwest China. Marine and Petroleum Geology, 2023, 147: 105996.

Li, J., Li, X., Wang, X., et al. Water distribution characteristic and effect on methane adsorption capacity in shale clay. International Journal of Coal Geology, 2016, 159: 135-154.

Li, M., Sun, M., Mohammadian, E., et al. Confinement effect in nanopores of shale and coal reservoirs: A review on experimental characterization methods. Gas Science and Engineering, 2024, 123: 205249.

Lin, H., Song, X., Sun, X., et al. Dynamic displacement of adsorbed methane by fracturing fluid during soaking in a shale gas reservoir based on low-field nuclear magnetic resonance. Journal of Petroleum Science and Engineering, 2022, 208: 109582.

Liu, B., Mastalerz, M., Schieber, J. SEM petrography of dispersed organic matter in black shales: A review. Earth-Science Reviews, 2022, 224: 103874.

Liu, Z., Liu, D., Cai, Y., et al. Application of nuclear magnetic resonance (NMR) in coalbed methane and shale reservoirs: A review. International Journal of Coal Geology, 2020, 218: 103261.

Loucks, R. G., Reed, R. M., Ruppel, S. C., et al. Spectrum of pore types and networks in mudrocks and a descriptive classification for matrix-related mudrock pores. AAPG Bulletin, 2012, 96(6): 1071-1098.

Ma, L., Fauchille, A. -L., Ansari, H., et al. Linking multiscale 3D microstructure to potential enhanced natural gas recovery and subsurface CO2 storage for Bowland shale, UK. Energy & Environmental Science, 2021, 14(8): 4481-4498.

Mastalerz, M., Drobniak, A., Hower, J. C. Controls on reservoir properties in organic-matter-rich shales: Insights from MICP analysis. Journal of Petroleum Science and Engineering, 2021, 196: 107775.

Milliken, K. L., Rudnicki, M., Awwiller, D. N., et al. Organic matter-hosted pore system, Marcellus Formation (Devonian), Pennsylvania. AAPG Bulletin, 2013, 97(2): 177-200.

Qin, C., Jiang, Y., Cao, M., et al. Experimental study on the methane desorption-diffusion behavior of Longmaxi shale exposure to supercritical CO2. Energy, 2023, 262: 125456.

Schaef, H. T., Glezakou, V. A., Owen, A. T., et al. Surface Condensation of CO2 onto Kaolinite. Environmental Science & Technology Letters, 2014, 1(2): 142-145.

Shaffer, G. Long-term effectiveness and consequences of carbon dioxide sequestration. Nature Geoscience, 2010, 3(7): 464-467.

Stavropoulou, E., Andò, E., Tengattini, A., et al. Liquid water uptake in unconfined Callovo Oxfordian clay-rock studied with neutron and X-ray imaging. Acta Geotechnica, 2019, 14: 19-33.

Sun, M., Duan, X., Liu, Q., et al. The importance of pore-fracture connectivity in overmature marine shale for methane occurrence and transportation. Marine and Petroleum Geology, 2023, 157: 106495.

Sun, M., Zhao, J., Pan, Z., et al. Pore characterization of shales: A review of small angle scattering technique. Journal of Natural Gas Science and Engineering, 2020, 78: 103294.

Thommes, M., Kaneko, K., Neimark, A. V., et al. Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure and Applied Chemistry, 2015, 87(9-10): 1051-1069.

Wang, Q., Hu, Q., Zhao, C., et al. Micro-to nano-scale areal heterogeneity in pore structure and mineral compositions of a sub-decimeter-sized Eagle Ford Shale. International Journal of Coal Geology, 2022, 261: 104093.

Wang, Y., Cheng, H. Advances in Microscopic pore structure characterization of fine-grained mudrocks. Energy & Fuels, 2023, 37(3): 1495-1510.

Webb, P. A. Volume and density determinations for particle technologists. Micromeritics Instrument Corp, 2001, 2: 1-16.

Xie, W., Gan, H., Chen, S., et al. Thermodynamic behavior of water vapor adsorption in shale and its dependence on organic matter and clay minerals. Fuel, 2023, 352: 129108.

Xu, H. Probing nanopore structure and confined fluid behavior in shale matrix: A review on small-angle neutron scattering studies. International Journal of Coal Geology, 2020, 217: 103325.

Yang, R., Jia, A., He, S., et al. Water adsorption characteristics of organic-rich Wufeng and Longmaxi Shales, Sichuan Basin (China). Journal of Petroleum Science and Engineering, 2020, 193: 107387.

Yang, Z., Zou, C., Fan, Y., et al. Basic properties and exploitation strategies of source rock strata. Advances in Geo-Energy Research, 2023, 10(2): 77-83.

Zeng, L., Vialle, S., Ennis-King, J., et al. Role of geochemical reactions on caprock integrity during underground hydrogen storage. Journal of Energy Storage, 2023, 65: 107414.

Zhang, C., Wang, Y., Kou, Z., et al. Recent research advances in enhanced CO2 mineralization and geologic CO2 storage. Advances in Geo-Energy Research, 2023, 10(3): 141-145.

Zhao, J., Hu, Q., Liu, K., et al. Pore connectivity characterization of shale using integrated wood’s metal impregnation, microscopy, tomography, tracer mapping and porosimetry. Fuel, 2020, 259: 116248.

Zhao, X., Sun, M., Ukaomah, C. F., et al. Pore connectivity and microfracture characteristics of Longmaxi shale in the Fuling gas field: Insights from mercury intrusion capillary pressure analysis. Gas Science and Engineering, 2023, 119: 205134.

Zou, S., Zhang, Y., Ma, L. Revealing subsurface dynamics: Imaging techniques for optimizing underground energy storage. Advances in Geo-Energy Research, 2024, 12(1): 1-7.

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Published

2024-03-27

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