Investigating rock properties and fracture propagation pattern during supercritical CO₂ pre-fracturing in conglomerate reservoir

Authors

  • Hang Zhou State Key Laboratory of Petroleum Resources and Engineering, China University of Petroleum, Beijing 102249, P. R. China; Faculty of Engineering-Civil and Environmental Engineering, University of Alberta, Edmonton, Alberta T6G 2R3, Canada
  • Tingwei Yan College of Petroleum, China University of Petroleum-Beijing at Karamay, Karamay 834000, P. R. China
  • Japan Trivedi Faculty of Engineering-Civil and Environmental Engineering, University of Alberta, Edmonton, Alberta T6G 2R3, Canada
  • Bo Wang* College of Petroleum, China University of Petroleum-Beijing at Karamay, Karamay 834000, P. R. China (Email: wangbo@cupk.edu.cn)
  • Fujian Zhou State Key Laboratory of Petroleum Resources and Engineering, China University of Petroleum, Beijing 102249, P. R. China

Abstract

Carbon dioxide pre-fracturing has shown high application potential in improving oil recovery in conglomerate reservoirs. However, the influence of CO₂ on the physical properties of reservoir rock and its diffusion behavior within the reservoir matrix have not been systematically studied. This paper integrates CO₂-saturated water soaking experiments, true triaxial fracturing experiments and field-scale tests to demonstrate that CO₂ soaking induces quartz reduction and clay mineral increase, leading to a decrease in porosity and mechanical strength. Clay-cemented conglomerates experience a greater loss in compressive strength and a higher reduction in permeability compared to calcareous-cemented counterparts under identical CO₂ soaking. In the horizontal principal stress direction, CO₂ fracturing achieves a greater fracture penetration depth than slickwater fracturing or CO₂ pre-injection followed by slickwater fracturing. CO₂ pre-fracturing reduces breakdown pressure by 15%-5% and increases fracture complexity. Field tests confirm a reduction in injection pressure and improved effective stimulation. However, dnarrower fracture width and higher tortuosity may limit proppant transportation.

Document Type: Original article

Cited as: Zhou, H., Yan, T., Trivedi, J., Wang, B., Zhou, F. Investigating rock properties and fracture propagation pattern during supercritical CO₂ pre-fracturing in conglomerate reservoir. Advances in Geo-Energy Research, 2025, 17(2): 95-106. https://doi.org/10.46690/ager.2025.08.02

Keywords:

Physicochemical mechanisms, conglomerate, CO₂ soaking, true triaxial fracturing, field-scale application

References

Abes, A., Michael, A. Experimental investigation of geochemical/petrophysical alteration chains from CO2 injection in dolomitic formations. Journal of Environmental Chemical Engineering, 2025, 13(4): 117102.

Agrawal, S., Sharma, M. M. Practical insights into liquid loading within hydraulic fractures and potential unconventional gas reservoir optimization strategies. Journal of Unconventional Oil and Gas Resources, 2015, 11: 60-74.

Al Kalbani, M., Serati, M., Hofmann, H., et al. Optimizing in-situ CO2 mineralisation: Geomechanics and scalability in dunite and serpentinite rocks-Examples from Australia and New Zealand. Science of The Total Environment, 2024, 927: 172277.

Al-Yaseri, A., Yekeen, N., Al-Mukainah, H. S., et al. Rock wettability impact on CO2-carbonate rock interaction and the attendant effects on CO2 Storage in carbonate reservoirs. Journal of Natural Gas Science and Engineering, 2022, 104: 104664.

Barnaji, M. J., Pourafshary, P., Rasaie, M. R. Visual investigation of the effects of clay minerals on enhancement of oil recovery by low salinity water flooding. Fuel, 2016, 184: 826-835.

Bennour, Z., Ishida, T., Nagaya, Y., et al. Crack extension in hydraulic fracturing of shale cores using viscous oil, water, and liquid carbon dioxide. Rock Mechanics and Rock Engineering, 2015, 48(4): 1463-1473.

Boggs, S. Jr. Principles of Sedimentology and Stratigraphy. London, UK, Pearson Education, 2014.

Chen, H., Kang, Y., Jin, W., et al. Numerical modeling of fracture propagation of supercritical CO2 compound fracturing. Journal of Rock Mechanics and Geotechnical Engineering, 2024, 16(7): 2607-2628.

de Jong, S. M., Spiers, C. J., Busch, A. Development of swelling strain in smectite clays through exposure to carbon dioxide. International Journal of Greenhouse Gas Control, 2014, 24: 149-161.

De Silva, G. P. D., Ranjith, P. G., Perera, M. S. A., et al. An experimental evaluation of unique CO2 flow behaviour in loosely held fine particles rich sandstone under deep reservoir conditions and influencing factors. Energy, 2017, 119: 121-137.

Fairhurst, C. On the validity of the ‘Brazilian’ test for brittle materials. International Journal of Rock Mechanics and Mining Sciences & Geomechanics Abstracts, 1964, 1(4): 535-546.

Feng, Y., Firoozabadi, A. Phase-field simulation of hydraulic fracturing by CO2 and water with consideration of thermoporoelasticity. Rock Mechanics and Rock Engineering, 2023, 56(10): 7333-7355.

Galdeano, C., Cook, M. A., Webber, M. E. Multilayer geospatial analysis of water availability for shale resources development in Mexico. Environmental Research Letters, 2017, 12(8): 084014.

Ha, S. J., Choo, J., Yun, T. S. Liquid CO2 fracturing: Effect of fluid permeation on the breakdown pressure and cracking behavior. Rock Mechanics and Rock Engineering, 2018, 51(11): 3407-3420.

Haimson, B. Micromechanisms of borehole instability leading to breakouts in rocks. International Journal of Rock Mechanics and Mining Sciences, 2007, 44(2): 157-173.

Huang, L., He, R., Yang, Z., et al. Exploring hydraulic fracture behavior in glutenite formation with strong heterogeneity and variable lithology based on DEM simulation. Engineering Fracture Mechanics, 2023, 278: 109020.

Ishida, T., Aoyagi, K., Niwa, T., et al. Acoustic emission monitoring of hydraulic fracturing laboratory experiment with supercritical and liquid CO2. Geophysical Research Letters, 2012, 39(16): 7705-8370.

Ishida, T., Chen, Y. Q., Bennour, Z., et al. Features of CO2 fracturing deduced from acoustic emission and microscopy in laboratory experiments. Journal of Geo physical Research: Solid Earth, 2016, 121(11): 8080-8098.

Kanakiya, S., Adam, L., Esteban, L., et al. Dissolution and secondary mineral precipitation in basalts due to reactions with carbonic acid. Journal of Geophysical Research: Solid Earth, 2017, 122(6): 4312-4327.

Kar, S., Chaudhuri, A. Influence of flow and geomechanics boundary conditions on hydraulic fracturing pattern and evolution of permeability between the wells. Engineering Fracture Mechanics, 2024, 298: 109949.

Khanlari, G. R., Heidari, M., Noori, M., et al. The effect of petrographic characteristics on engineering properties of conglomerates from Famenin Region, Northeast of Hamedan, Iran. Rock Mechanics and Rock Engineering, 2016, 49(7): 2609-2621.

Li, W., Frash, L. P., Carey, J. W., et al. Injection parameters that promote branching of hydraulic cracks. Geophysical Research Letters, 2021, 48(12): e2021GL093321.

Li, Y., Zhu, Y., Li, Z., et al. Shale oil recovery by CO2 injection in Jiyang Depression, Bohai Bay Basin, East China. Petroleum Exploration and Development, 2024, 51(4): 981-992.

Liu, K., Sheng, J., Zhang, Z. A simulation study of the effect of clay swelling on fracture generation and porosity change in shales under stress anisotropy. Engineering Geology, 2020, 278: 105829.

Min, Y., Jun, Y. Anorthite dissolution under conditions relevant to subsurface CO2 injection: effects of Na+, Ca2+, and Al3+. Environmental Science & Technology, 2016, 50(20): 11377-11385.

Mitchell, J., Chandrasekera, T. C., Holland, D. J., et al. Magnetic resonance imaging in laboratory petrophysical core analysis. Physics Reports, 2013, 526(3): 165-225.

Mukhametdinova, A., Karamov, T., Markovic, S., et al. Exploring in-situ combustion effects on reservoir properties of heavy oil carbonate reservoir. Petroleum Science, 2024, 21(5): 3363-3378.

Nooraiepour, M., Pola´ nski, K., Masoudi, M., et al. Potential for 50% Mechanical Strength Decline in Sandstone Reservoirs Due to Salt Precipitation and CO2-Brine Interactions During Carbon Sequestration. Rock Mechanics and Rock Engineering, 2025, 58(1): 1239-1269.

Patton, B. J., Pitts, F., Goeres, T., et al. Matrix acidizing case studies for the point arguello field. Paper SPE 83490 Presented at the SPE Western Regional/AAPG Pacific Section Joint Meeting, Long Beach, California, 19-24 May, 2003.

Perera, M. S. A., Ranjith, P. G., Peter, M. Effects of saturation medium and pressure on strength parameters of Latrobe Valley brown coal: Carbon dioxide, water and nitrogen saturations. Energy, 2011, 36(12): 6941-6947.

Rathnaweera, T. D., Ranjith, P. G., Perera, M. S. A., et al. An experimental investigation of coupled chemico-mineralogical and mechanical changes in varyingly-cemented sandstones upon CO2 injection in deep saline aquifer environments. Energy, 2017, 133: 404-414.

Trivedi, J., Babadagli, T. Efficiency analysis of greenhouse gas sequestration during miscible CO2 injection in fractured oil reservoirs. Environmental Science & Technology, 2008, 42(15): 5473-5479.

Wang, J., Ge, H., Liu, J., et al. Effects of gravel size and content on the mechanical properties of conglomerate. Rock Mechanics and Rock Engineering, 2022, 55(4): 2493-25020.

Warren, P. H., Taylor, G. J., Keil, K., et al. Petrology and chemistry of two “large” granite clasts from the Moon. Earth and Planetary Science Letters, 1983, 64(2): 175-185.

Wu, Y., Tao, J., Wang, J., et al. Experimental investigation of shale breakdown pressure under liquid nitrogen pre-conditioning before nitrogen fracturing. International Journal of Mining Science and Technology, 2021, 31(4): 611-620.

Zhou, H., Wang, B., Zhang, L., et al. Quantitative characterization and fracture morphology in reservoirs with various lithologies: An experimental investigation. Geoenergy Science and Engineering, 2024, 239: 212911.

Zhou, H., Yan, T., Ma, C. et al. Characteristics of propped fracture propagation in volcanic clastic reservoirs: a multiscale study of conductivity sustainability and fracture vetwork complexity. Rock Mechanics and Rock Engineering, 2025, 58(3): 1721-1735.

Downloads

Download data is not yet available.

Published

2025-07-16