Enhanced oil recovery via CO₂ flooding in tight reservoirs: A pore-scale analysis

Authors

  • Jinbao Liu State Key Laboratory of Petroleum Resources and Engineering, China University of Petroleum, Beijing 102249, P. R. China; College of Petroleum Engineering, China University of Petroleum, Beijing 102249, P. R. China
  • Danting Xiao State Key Laboratory of Petroleum Resources and Engineering, China University of Petroleum, Beijing 102249, P. R. China; College of Petroleum Engineering, China University of Petroleum, Beijing 102249, P. R. China
  • Jia Li State Key Laboratory of Petroleum Resources and Engineering, China University of Petroleum, Beijing 102249, P. R. China; College of Petroleum Engineering, China University of Petroleum, Beijing 102249, P. R. China
  • Linsong Cheng State Key Laboratory of Petroleum Resources and Engineering, China University of Petroleum, Beijing 102249, P. R. China; College of Petroleum Engineering, China University of Petroleum, Beijing 102249, P. R. China
  • Han Wang State Key Laboratory of Petroleum Resources and Engineering, China University of Petroleum, Beijing 102249, P. R. China
  • Jianchao Cai* State Key Laboratory of Petroleum Resources and Engineering, China University of Petroleum, Beijing 102249, P. R. China (Email: caijc@cup.edu.cn)

Abstract

CO₂ flooding has become a key technology for enhancing oil recovery in tight reservoirs, with great application potential. However, certain microscopic mechanisms of this technology still need to be further clarified. In this work, a multi-component and multi-phase lattice Boltzmann model based on the pseudopotential scheme is constructed considering different CO₂ flooding behaviors and verified for both immiscible and miscible phases, showing good agreement. On this basis, the effects of capillary numbers, extreme wetting at different velocities, Péclet numbers and injection patterns under fractured conditions on the CO₂ flooding process are systematically investigated. The results show that a larger capillary number enhances the displacement effect, whereas an excessively large value tends to cause viscous fingering, leading to accelerated CO₂ breakthrough. High-velocity extreme wetting conditions result in a higher displacement effect than low-velocity conditions. Moreover, an increase in displacement velocity weakens the wetting effect dominated by capillary force, thereby reducing the difference in oil recovery observed under high-velocity extreme wetting conditions. Different Péclet numbers dominate different fluid transport mechanisms. When the Péclet number is around the unity, the synergistic effects of molecular diffusion and viscous flow are balanced, jointly dominating fluid transport. The pore-fracture combined injection mode integrates the advantages of pore and fracture injections and effectively delays CO₂ breakthrough in the fracture system, resulting in an optimal displacement effect. This model can be extended to research on multiphase flow in tight and shale reservoirs as well as CO₂ geological sequestration.

Document Type: Original article

Cited as: Liu, J., Xiao, D., Li, J., Cheng, L., Wang, H., Cai, J. Enhanced oil recovery via CO₂ flooding in tight reservoirs: A pore-scale analysis. Advances in Geo-Energy Research, 2025, 17(2): 162-175. https://doi.org/10.46690/ager.2025.08.07

Keywords:

CO₂ flooding, tight reservoirs, lattice Boltzmann method, molecular diffusion, viscous flow

References

Alfarge, D., Wei, M., Bai, B. Factors affecting CO2-EOR in shale-oil reservoirs: Numerical simulation study and pilot tests. Energy & Fuels, 2017, 31(8): 8462-8480.

Bakhshian, S., Hosseini, S. A., Shokri, N. Pore-scale characteristics of multiphase flow in heterogeneous porous media using the lattice Boltzmann method. Scientific Reports, 2019, 9: 3377.

Cai, J., Jiao, X., Wang, H., et al. Multiphase fluid-rock interactions and flow behaviors in shale nanopores: A comprehensive review. Earth-Science Reviews, 2024, 257: 104884.

Chai, Z., Shi, B. Multiple-relaxation-time lattice Boltzmann method for the navier-stokes and nonlinear convection-diffusion equations: Modeling, analysis, and elements. Physical Review E, 2020, 102(2): 023306.

Chen, L., He, A., Zhao, J., et al. Pore-scale modeling of complex transport phenomena in porous media. Progress in Energy and Combustion Science, 2022a, 88: 100968.

Chen, L., Kang, Q., Mu, Y., et al. A critical review of the pseudopotential multiphase lattice boltzmann model: Methods and applications. International Journal of Heat and Mass Transfer, 2014, 76: 210-236.

Chen, H., Liu, X., Zhang, C., et al. Effects of miscible degree and pore scale on seepage characteristics of unconventional reservoirs fluids due to supercritical CO2 injection. Energy, 2022b, 239: 122287.

Chen, H., Yang, M., Huang, C., et al. A dynamic model of CO2 diffusion coefficient in shale based on the whole process fitting. Chemical Engineering Journal, 2022c, 428: 131151.

Diao, Z., Li, S., Liu, W., et al. Numerical study of the effect of tortuosity and mixed wettability on spontaneous imbibition in heterogeneous porous media. Capillarity, 2021, 4(3): 50-62.

Ezzatneshan, E., Goharimehr, R. A pseudopotential lattice Boltzmann method for simulation of two-phase f low transport in porous medium at high-density and high–viscosity ratios. Geofluids, 2021, 2021: 5668743.

Frank, F., Liu, C., Alpak, F. O., et al. Direct numerical simulation of flow on pore-scale images using the phase field method. SPE Journal, 2018, 23(5): 1833-1850.

Gogoi, S., Gogoi, S. B. Review on microfluidic studies for EOR application. Journal of Petroleum Exploration and Production Technology, 2019, 9(3): 2263-2277.

Guo, Z., Zheng, C., Shi, B. Discrete lattice effects on the forcing term in the lattice Boltzmann method. Physical Review E, 2002, 65(4): 046308.

Habibi, A., Yassin, M. R., Dehghanpour, H., et al. Experimen tal investigation of CO2-oil interactions in tight rocks: A montney case study. Fuel, 2017, 203: 853-867.

Huysmans, M., Dassargues, A. Review of the use of péclet numbers to determine the relative importance of advection and diffusion in low permeability environments. Hydrogeology Journal, 2005, 13(5): 895-904.

Jia, Z., Cao, R., Wang, B., et al. Effects of CH4/CO2 multi component gas on components and properties of tight oil during CO2 utilization and storage: Physical experiment and composition numerical simulation. Petroleum Science, 2023, 20(6): 3478-3487.

Lallemand, P., Luo, L. S. Theory of the lattice Boltzmann method: Dispersion, dissipation, isotropy, Galilean invariance, and stability. Physical Review E, 2000, 61(6): 6546.

Li, L., Zhang, D., Su, Y., et al. Microfluidic insights into CO2 sequestration and enhanced oil recovery in laminated shale reservoirs: Post-fracturing interface dynamics and micro-scale mechanisms. Advances in Geo-Energy Research, 2024, 13(3): 203-217.

Liu, X. Research progress in the evaluation of structural characteristics for tight oil reservoirs. Advances in Resources Research, 2023, 3(1): 1-16.

Liu, Y., Berg, S., Ju, Y., et al. Systematic investigation of corner flow impact in forced imbibition. Water Resources Research, 2022, 58(10): e2022WR032402.

Liu, Y., Min, J., Zhang, X. A novel micro-continuum lattice boltzmann approach for multiscale modeling immiscible two-phase flow in porous media. Physics of Fluids, 2024, 36(8): 083345.

Longde, S., Caineng, Z., Ailin, J., et al. Development characteristics and orientation of tight oil and gas in China. Petroleum Exploration and Development, 2019, 46(6): 1073-1087.

Michels, R., Siebert, D. N., dos Santos, L. O. E. Investigation on the influence of capillary number on drainage in porous media using a lattice Boltzmann method. Journal of Petroleum Science and Engineering, 2021, 205: 108918.

Milad, M., Junin, R., Sidek, A., et al. Huff-n-puff technology for enhanced oil recovery in shale/tight oil reservoirs: Progress, gaps, and perspectives. Energy & Fuels, 2021, 35(21): 17279-17333.

Ozowe, W., Daramola, G. O., Ekemezie, I. O. Recent advances and challenges in gas injection techniques for enhanced oil recovery. Magna Scientia Advanced Research and Reviews, 2023, 9(2): 168-178.

Sedahmed, M., Coelho, R., Warda, H. An improved multicomponent pseudopotential lattice Boltzmann method for immiscible fluid displacement in porous media. Physics of Fluids, 2022, 34(2): 023102.

Shan, X., Chen, H. Lattice boltzmann model for simulating f lows with multiple phases and components. Physical Review E, 1993, 47(3): 1815-1819.

Shi, K., Chen, J., Pang, X., et al. Wettability of different clay mineral surfaces in shale: Implications from molecular dynamics simulations. Petroleum Science, 2023, 20(2): 689-704.

Wang, H., Cai, J., Su, Y., et al. Pore-scale study on shale oil-CO2-water miscibility, competitive adsorption, and multiphase flow behaviors. Langmuir, 2023a, 39(34): 12226-12234.

Wang, Y., Cao, R., Jia, Z., et al. A multi-mechanism numerical simulation model for CO2-EOR and storage in fractured shale oil reservoirs. Petroleum Science, 2024, 21(3): 1814-1828.

Wang, F., Chang, S. Molecular dynamics investigation of shale oil occurrence and adsorption in nanopores: Unveiling wettability and influencing factors. Chemical Engineering Journal, 2024, 481: 148380.

Wang, H., Chen, L., Qu, Z., et al. Modeling of multi-scale transport phenomena in shale gas production– a critical review. Applied Energy, 2020, 262: 114575.

Wang, H., Kang, Q., Wang, W., et al. Oil-CO2 phase behavior in nanoporous media: A lattice boltzmann study. International Communications in Heat and Mass Transfer, 2025, 163: 108738.

Wang, D., Liu, F., Sun, J., et al. Lattice-Boltzmann simulation of two-phase flow in carbonate porous media retrieved from computed microtomography. Chemical Engineering Science, 2023b, 270: 118514.

Wang, H., Wang, W., Su, Y., et al. Lattice boltzmann model for oil/water two-phase flow in nanoporous media considering heterogeneous viscosity, liquid/solid, and liquid/liquid slip. SPE Journal, 2022, 27(6): 3508-3524.

Yang, J., Boek, E. S. A comparison study of multi-component lattice boltzmann models for flow in porous media ap plications. Computers & Mathematics with Applications, 2013, 65(6): 882-890.

Yin, Y., Zhang, H. Advances in tight oil reservoir development: A review of CO2 huff and puff technology. Advances in Resources Research, 2024, 4(3): 280-299.

Yiotis, A. G., Psihogios, J., Kainourgiakis, M. E., et al. A lattice boltzmann study of viscous coupling effects in immiscible two-phase flow in porous media. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2007, 300(1-2): 35-49.

Zhang, W., Feng, Q., Wang, S., et al. CO2-regulated octane f low in calcite nanopores from molecular perspectives. Fuel, 2021, 286: 119299.

Zhang, D., Li, L., Wang, H., et al. Study on the mechanism of CO2 huff-n-puff enhanced oil recovery and storage in shale porous media considering heterogeneous structure. Physics of Fluids, 2024, 36(7): 072005.

Zhang, L., Nowak, W., Oladyshkin, S., et al. Opportunities and challenges in CO2 geologic utilization and storage. Advances in Geo-Energy Research, 2023, 8(3): 141-145.

Zhang, C., Zhang, Q., Wang, W., et al. Capillary and viscous forces during CO2 flooding in tight reservoirs. Capillarity, 2022, 5(6): 105-114.

Zhao, J., Qin, F., Kang, Q., et al. A dynamic pore network model for imbibition simulation considering corner film flow. Water Resources Research, 2022, 58(7): e2022WR032332.

Zhou, Y., Guan, W., Zhao, C., et al. Numerical methods to simulate spontaneous imbibition in microscopic pore structures: A review. Capillarity, 2024, 11(1): 1-21.

Zhu, Q., Wu, K., Guo, S., et al. Pore-scale investigation of CO2-oil miscible flooding in tight reservoir. Applied Energy, 2024, 368: 123439.

Zuo, M., Chen, H., Qi, X., et al. Effects of CO2 injection volume and formation of in-situ new phase on oil phase behavior during CO2 injection for enhanced oil recovery (EOR) in tight oil reservoirs. Chemical Engineering Journal, 2023, 452: 139454.

Zou, Q., He, X. On pressure and velocity boundary conditions for the lattice Boltzmann BGK model. Physics of Fluids, 1997, 9(6): 1591-1598.

Downloads

Download data is not yet available.

Downloads

Published

2025-08-09

Issue

Section

Articles