Multifunctional nanofluids for enhanced oil recovery by simultaneous in situ mobility control and displacement efficiency improvement
Abstract
Compared with conventional chemical enhanced oil recovery methods, micro/nanofluidbased emulsion systems offer several advantages, including improved mobility control, enhanced stability, and effective modification of interfacial properties, while requiring lower chemical dosage and exhibiting better tolerance to harsh reservoir conditions. This study systematically evaluated the potential of a novel nanofluid-based emulsion as an enhanced oil recovery agent, with emphasis on its rheological behavior, emulsion stability, and interfacial performance. Rheological measurements demonstrate that emulsion viscosity is strongly influenced by the water-to-oil ratio and mixing duration. Systems with low oil content exhibit only modest viscosity changes, whereas increasing oil fraction and mixing time result in pronounced viscosity enhancement, indicating the formation of structured emulsion networks. This viscosity growth contributes to improved emulsion stability, which is further supported by microscopic observations revealing complex multiphase structures. Interfacial characterization shows that the nanofluid-based emulsion effectively lowers the oil-water interfacial tension and induces a strong wettability shift toward water-wet conditions, both of which are favorable for enhanced oil displacement. Microfluidic displacement experiments provide pore-scale evidence that the combined effects of viscosity enhancement, improved emulsion stability, interfacial tension reduction, and wettability alteration lead to efficient mobilization of residual oil. Visual observations confirm in situ emulsion formation within the porous network and improved sweep behavior compared with conventional water injection. Overall, the results highlight the multifunctional role of nanofluid-based emulsions in stabilizing flow, enhancing sweep efficiency, and modifying interfacial dynamics, demonstrating their strong potential as an advanced chemical strategy for enhanced oil recovery applications.
Document Type: Original article
Cited as: Ovsepian, M., Salami, Y., Karamov, T., Du, D., Dobysh, I., Cheremisin, A., Yuan, C. Multifunctional nanofluids for enhanced oil recovery by simultaneous in situ mobility control and displacement efficiency improvement. Advances in Geo-Energy Research, 2026, 19(3): 231-241. https://doi.org/10.46690/ager.2026.03.03
DOI:
https://doi.org/10.46690/ager.2026.03.03Keywords:
Chemical enhanced oil recovery, emulsion flooding, microemulsions, nanoparticles, emulsion stabilityReferences
Alnarabiji, M. S., Yahya, N., Nadeem, S., et al. Nanofluid enhanced oil recovery using induced ZnO nanocrystals by electromagnetic energy: Viscosity increment. Fuel, 2018, 233: 632-643.
Behera, U. S., Poddar, S., Deshmukh, M. P., et al. Comprehensive review on the role of nanoparticles and nanofluids in chemical enhanced oil recovery: Interfacial phenomenon, compatibility, scalability, and economic viability. Energy and Fuels, 2024, 38(15): 13760-13795.
Bijani, M., Khamehchi, E., Shabani, M. Comprehensive experimental investigation of the effective parameters on stability of silica nanoparticles during low salinity water flooding with minimum scale deposition into sandstone reservoirs. Scientific Reports, 2022, 12(1): 16472.
Chevalier, R. C., Gomes, A., Cunha, R. L. Role of aqueous phase composition and hydrophilic emulsifier type on the stability of W/O/W emulsions. Food Research International, 2022, 156: 111123.
Dongmei, W., Namie, S., Seright, R. Pressure modification or barrier issues during polymer flooding enhanced oil recovery. Geofluids, 2022, 2022: 6740531.
Dorhjie, D. B., Pereponov, D., Aminev, T., et al. A microfluidic and numerical analysis of non-equilibrium phase behavior of gas condensates. Scientific Reports, 2024, 14(1): 9500.
Du, D., Hou, S., Pu, W., et al. Investigation on enhanced oil recovery potential of active nano-SiO₂ in high-temperature and high-salinity reservoirs at core and pore scale. Fuel, 2026, 404: 136363.
Du, D., Li, J., Pu, W., et al. Experimental study on EOR potential of in-situ water in oil emulsion in low-temperature conglomerate reservoirs. Geoenergy Science and Engineering, 2024, 241: 213097.
Filippov, S. K., Khusnutdinov, R., Murmiliuk, A., et al. Dynamic light scattering and transmission electron microscopy in drug delivery: A roadmap for correct characterization of nanoparticles and interpretation of results. Materials Horizons, 2023, 10(12): 5354-5370.
Ganat, T., Ali, I. Mobility control requirement in EOR processes, in Advancements in Chemical Enhanced Oil Recovery, edited by T. Sharma, K. R. Chaturvedi, T. Ganat and I. Ali, Apple Academic Press, Palm Bay, pp. 225-244, 2024.
Gong, Y., Li, L., Huang, W., et al. A study of alkali-silica nanoparticle-polymer (ANP) flooding for enhancing heavy oil recovery. Journal of Petroleum Science and Engineering, 2022, 213: 110465.
Hassani, K., Zheng, W., Rostami, B. Rock wettability and interfacial tension improvement by exposure time effect in modified water injection process coupled with silica nanoparticles. Petroleum Science and Technology, 2024, 42(9): 1031-1046.
Hu, X., Long, Y., Xuan, G., et al. Optimized hydrophobic magnetic nanoparticles stabilized Pickering emulsion for enhanced oil recovery in complex porous media of reservoir. Frontiers in Energy Research, 2023, 11: 1212664.
Jang, H., Lee, W. S., Lee, J. Performance evaluation of surface-modified silica nanoparticles for enhanced oil recovery in carbonate reservoirs. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2024, 681: 132784.
Karambeigi, M. S., Abbassi, R., Roayaei, E., et al. Emulsion flooding for enhanced oil recovery: Interactive optimization of phase behavior, microvisual and core-flood experiments. Journal of Industrial and Engineering Chemistry, 2015, 29: 382-391.
Khlaifat, A. L., Fakher, S., Harrison, G. H. Evaluating factors impacting polymer flooding in hydrocarbon reservoirs: Laboratory and field-scale applications. Polymers, 2024, 16(1): 75.
Khormali, A., Koochi, M. R., Varfolomeev, M. A., et al. Experimental study of the low salinity water injection process in the presence of scale inhibitor and various nanoparticles. Journal of Petroleum Exploration and Production Technology, 2023, 13(3): 903-916.
Kumar, A., Kaur, R., Kumar, V., et al. New insights into water-in-oil-in-water (W/O/W) double emulsions: Properties, fabrication, instability mechanism, and food applications. Trends in Food Science and Technology, 2022, 128: 2237.
Liu, R., Deng, J., Pu, W., et al. Micro- and macroscopic experiments on self-adaptive mobility control and displacement efficiency of carbon-based composite nanofluid for enhanced oil recovery. Petroleum, 2025, 11(2): 211-225.
Lu, Z., Wang, L., Guo, Z., et al. The microfluidic in geoenergy resources: Current advances and future perspectives. Advances in Geo-Energy Research, 2025, 16(2): 171-180.
Mansouri Zadeh, M., Amiri, F., Hosseni, S., et al. Synthesis of colloidal silica nanofluid and assessment of its impact on interfacial tension and wettability for enhanced oil recovery. Scientific Reports, 2024, 14(1): 325.
Mumbere, W., Sagala, F., Gupta, U., et al. Reservoir potential unlocked: Synergies between low-salinity water flooding, nanoparticles and surfactants in enhanced oil recovery - A review. ACS Omega, 2025, 10(29): 31216-31261.
Nyah, F., Ridzuan, N., Ikechukwu Nwaichi, P., et al. Comprehensive review on the role of salinity on oil recovery mechanisms during chemical flooding. Journal of Molecular Liquids, 2024, 415: 126308.
Pang, Q., Pu, W., Tang, X., et al. Experimental investigation and simulation of W/O emulsion flow in nanofluid flood for enhanced oil recovery. Geoenergy Science and Engineering, 2024, 239: 212973.
Pu, W., He, Y., Liu, R., et al. Functionalized silica nanoparticles for enhanced heavy oil recovery: Experiment and molecular dynamics simulation. Energy and Fuels, 2025, 39(29): 14055-14069.
Qin, T., Goual, L., Piri, M., et al. Nanoparticle-stabilized microemulsions for enhanced oil recovery from heterogeneous rocks. Fuel, 2020, 274: 117830.
Santos, L. B. L., Silva, A. C. M., Pereira, K. R. O., et al. Microemulsions stabilized with nanoparticles for EOR: A review. Journal of Molecular Liquids, 2023, 391: 123271.
Sepahvand, M., Ghalenavi, H., Salari Goharrizi, F., et al. Integrating low salinity water, surfactant solution, and functionalized magnetite nanoparticles with natural acidic groups for enhanced oil recovery: Interfacial tension study. Journal of Molecular Liquids, 2024, 405: 124944.
Shakeel, M., Sagandykova, D., Mukhtarov, A., et al. Maximizing oil recovery: Innovative chemical EOR solutions for residual oil mobilization in Kazakhstan’s waterflooded sandstone oilfield. Heliyon, 2024, 10(7): e28915.
Souza, T. G. F., Ciminelli, V. S. T., Mohallem, N. D. S. A comparison of TEM and DLS methods to characterize size distribution of ceramic nanoparticles. Journal of Physics: Conference Series, 2016, 733(1): 012039.
Sze Lim, S. S., Elochukwu, H., Nandong, J., et al. A review on the mechanisms of low salinity water/surfactant/nanoparticles and the potential synergistic application for c-EOR. Petroleum Research, 2023, 8(3): 324-337.
Wang, D., Han, P., Shao, Z., et al. Sweep-improvement options for the Daqing Oil Field. SPE Reservoir Evaluation and Engineering, 2008, 11(1): 18-26.
Wen, Y., Zhang, C., Zhu, G., et al. Combined effects of nanofluid and surfactant on enhanced oil recovery: An experimental study. ACS Omega, 2025, 10(44): 52375-52386.
Wu, H., Chang, J., Xu, G., et al. In-situ emulsification and viscosification system of surfactant-assisted Janus nanofluid and its profile control effect. Advances in Geo-Energy Research, 2024, 14(2): 135-146.
Yang, L., Ge, J., Wu, H., et al. Study on the enhanced oil recovery properties of the pickering emulsions for harsh reservoirs. ACS Omega, 2024, 9(49): 48427-48437.
Zhi, Z., Liu, R., Wang, W., et al. Recent progress in oil-in-water-in-oil (O/W/O) double emulsions. Critical Reviews in Food Science and Nutrition, 2023, 63(23): 6196-6207.
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Copyright (c) 2026 Mkhitar Ovsepian, Yusuff Salami, Tagir Karamov, Daijun Du, Ilya Dobysh, Alexey Cheremisin, Chengdong Yuan

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